The College of Education started as the School of Education (SEd) in 1992 under the supervision of Dr. Constancia G. Cueno as Dean. During its first year of operation, it had a faculty contingent of 44 and an enrollment of 343 students.

Initially, SEd offered the programs Bachelor of Secondary Education (BSE) with Mathematics, Biology, Chemistry, Home Economics and Technology, P.E. and Recreation, and Agricultural Arts as major fields; and Bachelor of Elementary Education (BEE) with Mathematics, Science Home Economics and Technology, P.E. and Recreation, and Work Education as areas of specialization. It maintained the high school project, the Secondary Education Laboratory School as a laboratory school for its BSE students. The graduate program, Master of Arts in Education was maintained in coordination with the Office of the Graduate Studies. The program offered majors in Elementary Education, Secondary Education, and Science Education with specialization in Mathematics, Chemistry and Biology. In 1994, SEd started to offer Diploma in Hotel and Restaurant Management (DHRM). In 1995, it established a special project, the Child Development Center (CDC) which admitted elementary pupils.

In 1996, Dr. Lorna L. Penales was designated as the new dean of SEd. New developments were implemented. In 1997, the four-year degree program, Bachelor of Science in Hotel and Restaurant Management (BSHRM), began to be offered by virtue of the Board of Trustees Resolution No. 54, s. 1996. This was followed by the offerings of the two-year non-degree program, Diploma in Tourism Management (DTM), the Certificate in Garments Technology (CGT), the Certificate in Fibercraft Technology (CFT), and the Certificate in Cosmetology (CCoS). The Laboratory School Curriculum was also revised and changed to Science Curriculum. In 1998, SEd started to offer another degree program, the Bachelor in Physical Education (BPE). The doctoral program, Ph.D. in Education was also offered in coordination with the Office of Graduate Studies.

With the conversion of Don Severino Agricultural College into a state university, the Cavite State University, in January 1998, the School of Education was then eventually elevated into a college, the College of Education. In the same year, CDC was formally subsumed under CEd. However, CDC continued to finance its own personal services and other operating expenses. On the other hand, the Physical Education Department was elevated into a separate college, now called the College of Sports, Physical Education and Recreation (CSPEAR). CEd also established various income generating and instructional projects such as the Ornamental Garden, the CEd Science Mini-Centrum, and the University Bakeshoppe, the latter which functions both as an income-generating project and as laboratory for H.E. and HRM students. The College also fully operationalized the Multipurpose Quadrangle as the venue of the various functions and in-door activities in the University.

The year 1998 also saw the College preparing for Level I accreditation by Accrediting Agency of Chartered Colleges and Universities in the Philippines, Inc. (AACCUP) of its B.S.E. and B.E.E. Programs.